应用化学与工业催化
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张晓梅
发布时间:2018年09月01日 08:20    作者:化学与化工学院    点击:[]

【个人简介】

  • 姓  名:张晓梅
  • 职  称:教授、博士生导师

    学科专业:应用化学

    电  话:0531-88363693

    E-mailzhangxiaomei@sdu.edu.cn

【学习及工作经历】

  • 2014.5~至今     山东大学化学与化工学院            教授
  • 2007.72014.4    山东大学化学与化工学院             副教授

    2003.72007.7    山东大学化学与化工学院             讲师

    2000.92003.7    北京大学化学与分子工程学院   理学博士

    1997.92000.7    青岛科技大学应用化学专业    工学硕士

    1993.91997.7    青岛科技大学应用化学专业    工学学士

【主讲课程】

  •  本科生
  • 《化工过程开发概要》

    《化工基础实验》


  •  研究生
  • 《高等精细有机合成》


【研究领域和兴趣】

  •  1.多功能纳米多孔材料的设计与制备。

  •     研究重点是通过分子设计,构筑具有大比表面积、丰富表面基团和高吸附容量的多孔有机聚合物材料,探索其在废水处理,环境保护等方面的应用。

    2.基于卟啉的纳米复合材料在生物医学领域的应用。

  •         主要致力于设计新型的卟啉基多孔有机聚合物材料,利用卟啉衍生物优异的仿生催化性能,并通过分子设计引入荧光,磁性等性能,设计合成新型的卟啉基纳米复合材料。在此基础上,创建用于检测生物分子和重要生命化学反应的新型高灵敏度与高选择性生物传感体系,同时探索用于疾病早期诊断和治疗的新技术。

     


【主要论著】

  • 1.       Xiao Deng,Yishan Fang,Sha Lin,Qian Cheng,Qingyun Liu,* Xiaomei Zhang*"Porphyrin-BasedPorous Organic Frameworks as a Biomimetic Catalyst for Highly EfficientColorimetric Immunoassay" ACS Appl.Mater. Interfaces 2017, 9, 3514-3523.

    2.       TingtingLiu, Xinyuan Hu, Yanfeng Wang,* Liyang Meng, Yanan Zhou, Jixiang Zhang,Min Chenb,* Xiaomei Zhang,*“Triazine-based covalent organic frameworks for photodynamic inactivation ofbacteria as type-II photosensitizers”, J.Photochemistry & Photobiology, B: Biology, 2017, 175, 156-162.

    3.       YuxiaHou, Xiaomei Zhang, Chiming Wang,Dongdong Qi, Yongqing Gu, Ziqian Wang, Jianzhuang Jiang,* “Novel imine-linkedporphyrin covalent organic frameworks with good adsorption removing propertiesof RhB”, New J. Chem., 2017, 41, 6145-6151.

    4.       ShaLin, Lisha Ji, Lu Jing, Jitao Lu, Haoliang Wang, Shuzhuang Sun, Fanyi Kong, Xiaomei Zhang* “Helical self-assemblyand nonlinear optical properties of two optically active phthalocyaninederivatives with the same chiral substituents on the α or β position” Inorganica Chimica Acta, 2015, 434, 24-30.

    5.       YuxiaHou, Yingzhong Zhu, Junshan Sun, Xiaomei Zhang,* Yupeng Tian,*Jianzhuang Jiang*“Self-assembly and Nonlinear Optical Properties of(µ-Oxo)bis[meso-tetrakis(p-bromophenyl-porphyrinato)iron(III)” CrystEngComm., 2015,17, 4699–4704.

    6.       YuxiaHou, Xiaomei Zhang*, Junshan Sun,Sha Lin, Dongdong Qi, Runrun Hong, Dianqing Li, Xin Xiao, Jianzhuang Jiang* “GoodSuzuki-coupling Reaction Performance of Pd Immobilized at the Metal-freePorphyrin-based Covalent Organic Framework” Microporousand Mesoporous Materials, 2015, 214, 108-114.

    7.       ShaLin, Yuxia Hou, Xiao Deng, Haoliang Wang, Shuzhuang Sun, Xiaomei Zhang* “A triazine-based covalent organicframework/palladium hybrid for one-pot silicon-based crosscoupling of silanesand aryl iodides” RSC Adv., 2015, 5, 41017-41024.

    8.       ZhiwenLi, Xiaohong Xu, Xiaomei Zhang* “Oxidationof Organosilanes with Nanoporous Copper as a Sustainable Non-Noble-MetalCatalyst” ChemPhysChem 2015, 16, 1603 –1606.

    9.       ZhiwenLi, Xiaohong Xu, Xiaojian Jiang, Yingchun Li, Zhixin Yu, Xiaomei Zhang* “Facile reduction of aromatic nitro compounds to aromaticamines catalysed by support-free nanoporous silver” RSC Adv., 2015, 5, 30062-30066.

    10.   JitaoLu,* Qingguo Meng, Liangliang Zhang, Yitong Liu, Wenjie Liu, Xiaomei Zhang* “Single crystalstructure, self-assembled nano-structure and semiconductor properties of asandwich-type mixed (phthalocyaninato)(porphyrinato) europium triple-decker complex”Dyes and Pigments, 2015, 115, 1-6.

    11.   PeihuaZhu*, Lingling Kan, Xinyu Han, Jijun Feng, Jingna Jia, Xiaomei Zhang* “Organic nanostructures with controllable morphologyfabricated from ferroceneeporphyrin derivatives: Effect of metal-ligandcoordination on the morphology, dimension and nonlinear optical properties” Dyes and Pigments 2015, 113, 55-60.

    12.   ZhiwenLi, Congcong Zhang, Jing Tian, Zhonghua Zhang, Xiaomei Zhang*, Yi Ding, “Highly selective oxidation oforganosilanes with a reusable nanoporous silver catalyst” Catalysis Communications 2014,53, 53-56.

    13.   ZhiwenLi, Sha Lin, Lisha Ji, Zhonghua Zhang, XiaomeiZhang*, Yi Ding* “Nanoporous palladium catalyzed silicon-based one-potcross-coupling reaction of aryl iodides with organosilanes” Catal. Sci. Technol., 2014, 4, 1734–1737.

    14.   Fei Yang, Lu Jing, Lisha Ji, Xiaomei Zhang*, “Design,Fabrication and the Relative Catalytic Properties of Mental-organic Framework ComplexesBased on Tetra(4-carboxyphenyl)porphyrin and Cerium Ions” CrystEngComm., 2014,16, 4274–4280.

    15.   Lisha Ji,Lu Jing, Sha Lin, Xiao Deng, Peihua Zhu, Xiaomei Zhang*, “HelicalSelf-assembly of Optically Active Phthalocyanine Derivatives in Mesophase. Effect of the Positionof Chiral Substituents on the Handedness and Mesophase TexturesDyes and Pigments, 2014, 106, 176-181.

    16.   CongcongZhang, Lu Jing, Sha Lin, Zijuan Hao, Jing Tian, Xiaomei Zhang,* Peihua Zhu*“Helical Nano-structures Self-assembled from Optically Active PhthalocyanineDerivatives. Effect of Metal-ligand Coordination Bond on the Morphology andHandedness of Self-assembled Nano-structures” ChemPhysChem, 2013, 14, 3827-3833.

    17.   JingTian, Lu Jing, Congcong Zhang, Lisha Ji, Peihua Zhu, Xiaomei Zhang* “HelicalSelf-assembly of Optically Active Phthalocyanine Derivatives Bearing FourOptically Active (S)-2-methylbutoxyMoieties on the α-Position of thePhthalocyanine Ring” Eur. J. Inorg. Chem.2013, 5281-5287.

    18.   JingTian, Lu Jing, Lisha Ji, Congcong Zhang, Qingyun Liu, Xiaomei Zhang* “HelicalSelf-assembly and Nonlinear Optical Properties of Optically ActivePhthalocyanine Derivatives Bearing Eight Optically Active Diethyleneglycol mono-(S)-2-methylbutyl Ether Moieties on the β-Position of the Phthalocyanine Ring” Rsc Adv. 2013, 3, 22461-22468.

    19.   XiaomeiZhang, Yi Ding* “Unsupported Nanoporous Gold for Heterogeneous Catalysis” Catal. Sci. Technol., 2013, 3, 2862–2868.

    20.   ZhiwenLi, Junling Xu, Xiaohu Gu, Kang Wang, Wenhui Wang, Xiaomei Zhang, ZhonghuaZhang, Yi Ding* “Selective Gas-Phase Oxidation of Alcohols over NanoporousSilver” ChemCatChem 2013, 5, 1705 – 1708.

    21.   RanranSun, Liang Wang, Jing Tian, Xiaomei Zhang,* Jianzhuang Jiang,* “Self-assemblednanostructures of optically active phthalocyanine derivatives. Effect ofcentral metal ion on the morphology, dimension, and handedness” Nanoscale2012, 4, 6990-6996.

    22.   ZijuanHao, Xingcui Wu, Ranran Sun, Changqin Ma, Xiaomei Zhang* Morphology Controlled Nanostructures Self-Assembledfrom Phthalocyanine Derivatives Bearing Alkylthio Moieties: Effect ofSulfur-Sulfur and Metal-Ligand Coordination on Intermolecular StackingChemPhysChem 2012, 13,267-273.

    23.   JitaoLu, Lizhen Wu, Lu Jing, Xiaohong Xu, Xiaomei Zhang,* “Synthesis,circular dichroism, and third-order nonlinear optical properties of opticallyactive porphyrin derivatives bearing four chiral citronellal moieties” Dyesand Pigments, 2012, 94, 169-174.

    24.   JitaoLu, Ranran Sun, Min Chen, Xiaohong Xu, Xiaomei Zhang,* “Design,synthesis, and self-assembly of optically active perylenetetracarboxylic diimidebearing two peripheral chiral binaphthyl moieties” Mat. Sci .Eng. C-Mater.2012, 32, 1948-1954.

    25.   RanranSun, Xingcui Wu, Zijuan Hao, Xiaomei Zhang,* “Crystal structure andself-assembly property of sandwich-type mixed (phthalocyaninato)(porphyrinato)rare earth double-decker complexes” Inorganica Chimica Acta 2012,384, 204-209.

    26.    Quanbo Wang, YanliChen, Pan Ma, Jitao Lu, Xiaomei Zhang,*Jianzhuang Jiang* Morphology andchirality controlled self-assembled nanostructures of porphyrin–pentapeptideconjugate: effect of the peptide secondary conformationJ. Mater. Chem., 2011, 21, 8057–8065.

    27.    Jitao Lu,Pan Ma,XiaomeiZhang,*Jianzhuang Jiang*Sandwich-type(phthalocyaninato)(porphyrinato) europium triple-decker nanotubes. Effects ofthe phthalocyanine peripheral substituents on the molecular packingDalton Trans., 2011, 40, 12895–12900.

    28.    Peihua Zhu, Pan Ma, Yan Wang, Quanbo Wang, Xian Zhao,* Xiaomei Zhang*Organic Nanostructureswith Controllable Morphology Fabricated from Ferrocene–Porphyrin Derivatives:Effect of Metal–Ligand Coordination on the Morphology, Dimensions, andSemiconductor Properties of Self-Assembled NanostructuresEur. J. Inorg. Chem. 2011, 4241–4247.

    29.   Jitao Lu,HailongWang,XiaomeiZhang,* Synthesisand Crystal Structure of a Mixed (Phthalocyaninato)(porphyrinato) Yttrium Double-deckerComplexChinese J. Struct. Chem.2011,30, 872-876.

    30.   Jitao Lu, Yanhua Deng, Xiaomei Zhang,*Nagao Kobayashi, Jianzhuang Jiang,*“Optically Active Mixed (Phthalocyaninato)(porphyrinato) Rare Earth Triple-deckerComplexes. Synthesis, Spectroscopy, and Effective Chiral Information Transfer” Inorg. Chem. 2011, 50, 2562-2567.

    31.   XingcuiWu, Wei Lv, Quanbo Wang, Hailong Wang, XiaomeiZhang,* Jianzhuang Jiang,* “Sandwich-type Mixed (Phthalocyaninato)(porphyrinato)Rare Earth Double-decker Complexes with Decreased Molecular Symmetry of Cs: Single Crystal Structure and Self-assembled Nano-structure”Dalton. Trans. 2011, 40, 107-113.

    32.   WeiLv,Peihua Zhu, Yongzhong Bian, Changqin Ma, Xiaomei Zhang,* Jianzhuang Jiang,* “Optically ActiveHomoleptic Bis(phthalocyaninato) Rare Earth Double-Decker Complexes BearingPeripheral Chiral Menthol Moieties: Effect of π-π Interaction on the ChiralInformation Transfer at the Molecular Level” Inorg. Chem. 2010, 49, 6628-6635.

    33.   Xiaomei Zhang, Quanbo Wang, Lizhen Wu, Wei Lv, Jitao Lu, YongzhongBian, Jianzhuang Jiang,* “OrganicNanostructures with Controllable Morphology Fabricated from Mixed(Phthalocyaninato)(porphyrinato) Europium Double-Decker ComplexesJ. Phys. Chem. B 2010, 114, 1233-1240.

    34.   LizhenWu,Quanbo Wang, Jitao Lu, Yongzhong Bian, Jianzhuang Jiang,*Xiaomei Zhang,*HelicalNanostructures Self-Assembled from Optically Active Phthalocyanine DerivativesBearing Four Optically Active Binaphthyl Moieties: Effect of Metal−LigandCoordination on the Morphology, Dimension, and Helical Pitch of Self-AssembledNanostructuresLangmuir, 2010,26, 7489-7497.

    35.   JitaoLu, Lizhen Wu, Jianzhuang Jiang,*Xiaomei Zhang,* “Helical Nanostructures of Optically Active MetalFree Porphyrin with Four Optically Active Binaphthyl Moieties. Effect ofMetal-ligand Coordination on the Morphology” Eur. J. Inorg. Chem. 2010,4000-4008.

    36.   JitaoLu, Daopeng Zhang, Hailong Wang, Jianzhuang Jiang,*Xiaomei Zhang,* “Synthesis, Crystal Structure andSelf-assembly Property of A Mixed (Phthalocyaninato)(porphyrinato) EuropiumTriple-decker Complex” Inorg. Chem.Commun. 2010, 13, 1144-1147.

    37.    XiaomeiZhang, Jiang, J. Z.Chapter: “Rare Earth Coordination Chemistry: Fundamentals and Applications”Eds: Huang C.-H. Whiley Press. 2010, 137-193.

    38.   GuifenLu, Xiaomei Zhang,* Xue Cai,Jianzhuang Jiang,* “Tuning the Morphology of Self-Assembled Nanostructures ofAmphiphilic Tetra(p-hydroxyphenyl)Porphyrins with Hydrogen Bonding andMetal-Ligand Coordination Bonding” J.Mater. Chem. 2009, 19,2417-2424.

    39.   WeiLv, Xingcui Wu, Yongzhong Bian, Jianzhuang Jiang,*XiaomeiZhang,* “Helical Fibrous Nanostructures Self-Assembled from Metal-FreePhthalocyanine with Peripheral Chiral Menthol Units” chemphyschem2009, 10, 2725-2732.

    40.    Xiaomei Zhang, Atsuya Muranaka, Wei Lv, Yuexing Zhang, YongzhongBian, Jianzhuang Jiang,*Nagao Kobayashi,* “Optically Active Mixed(Phthalocyaninato)(porphyrinato) Rare Earth Double-Decker Complexes. Synthesis,Spectroscopy, and Solvent DependentMolecular ConformationChem Eur. J., 2008, 14, 4667-4674.

    41.    WeiLv, Xiaomei Zhang,* Jitao Lu,Yuexing Zhang, Xiyou Li, Jianzhuang Jiang,* “Synthesis and ControllableSupramolecular Assembly of Novel Optically Active Metal-free PhthalocyanineDerivatives” Eur. J.Inorg. Chem. 2008, 4255-4261.

     
  •  

【科研项目】

  •  作为项目负责人承担的课题:

    8.  国家自然科学基金面上项目,基于卟啉骨架分子的共价有机框架的设计、制备及功能化研究,(批准号:21472117),2015/01-2018/12

    7. 横向项目,盐湖卤水中萃取锂高性能新型萃取剂的研发, 2016/02-2017/02

    6. 国家自然科学基金面上项目,手性卟啉酞菁类夹心稀土配合物分子功能材料的设计、制备与性能研究,(批准号:21171106),2012/01-2015/12

    5. 国家自然科学基金青年基金,手性大环配位化合物的设计合成、组装及功能性质关系的研究(批准号:20801031),2009/01-2011/12

    4.  山东省自然科学基金青年基金(批准号:Q2008B01

    3.  山东省博士后科研项目择优资助(批准号:200603070

    2.  中国博士后科学基金(批准号:20070411093

    1.  山东省优秀中青年科学家奖励基金(批准号:2007BS04027

      


【科研成果】

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【所获专利】

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【联合培养情况】

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【拟招收研究生情况】

  •  每年拟在无机化学专业招收博士研究生1名,在应用化学招收硕士研究生1名,在化学工程(专业学位) 招收硕士研究生1名。
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