• 电话:0531-88364464

  • 传真:0531-88564464

  • 地址:
    中国山东省济南市山大南路27号
  • 邮编:250100



导师风采

【个人简介】

孙頔(Sun Di),男,1983年9月出生,博士, 无机化学研究所 博士生导师。


联系电话: 0531-88364218


手机:13854137508


邮箱:dsun@sdu.edu.cn


地址:山东省济南市历城区山大南路27号化学新楼415室


English website: http://opcl.sdu.edu.cn/Teacher.aspx?tid=5


学术团体兼职:


Journal of Crystallography  


Journal of Materials Science & Research 编委


【学习及工作经历】

学习经历:


2001年-2005年,聊城大学,化学化工学院,本科/理学学士


2005年-2008年,厦门大学,化学化工学院,研究生/理学硕士 (导师:黄荣彬&郑兰荪)


2008年-2011年,厦门大学,化学化工学院,研究生/理学博士 (导师:郑兰荪)

工作经历:


2011年7月-2014年8月, 山东大学,化学化工学院,讲师,硕士生导师

 

2014年9月-至今, 山东大学,化学化工学院,副教授,硕士生导师



 


【主讲课程】


<无机化学新兴领域导论之X-射线单晶结构解析>


<有机化学实验>


<化学与健康>


【研究领域和兴趣】

配位化学及晶体工程

 

超分子化合物(共晶化合物,主-客体化合物)

溶剂分子簇(水分子簇,阴离子水簇)

 

原子簇化学(金属原子簇合物,贵金属纳米颗粒原子级结构的研究)

 

异金属簇合物及聚合物(基于银簇分子的杂金属化合物)

 

压、热致荧光变色配(簇)合物及构效关系阐述


多酸簇合物分子结构、组装及相关性质研究


本课题组一直致力于功能配(簇)合物的设计、可控制备与性能研究;在合成方法学的探索、结构调变机制、组装机理、构效关系阐明等方面取得了多项具有创新性的科研成果。自2009至今,在国际期刊,如J. Am. Chem. Soc., Angew. Chem. Int. Ed., Chem. Commun., Chem. Eur. J., Inorg. Chem., Dalton Trans.,发表SCI论文152篇,其中以第一作者或通讯作者身份发表SCI论文114篇,影响因子3.0以上63篇。论文被国内外学术同行在Chem. Rev.Chem. Soc. Rev., Angew. Chem. Int. Ed., J. Am. Chem. Soc.等几十种国际刊物上近五年他引1500余次。

 

【主要论著】

全部论文详见:My Research ID: http://www.researcherid.com/rid/G-3352-2010

(Total ISI citations: 3594;  H-index: 35, last updated on Dec. 28, 2016)

2017年

[1]  H. Zhang, L.-Y. Guo, J. Jiao, X. Xin,* D. Sun,* S. L. Yuan,* Ionic Self-assembly of  Polyoxometalate-Dopamine Hybrid Nanoflowers with Excellent Catalytic Activity for Dyes, ACS Sustainable Chemistry & Engineering 5 (2017) 1358-1367.




[2] S. S. Zhang, H. F. Su, Z. Wang, L. Wang, Q. Q. Zhao, C.-H. Tung, D. Sun,* L. S. Zheng, Anion-Templated Nanosized Silver Alkynyl Clusters: Cluster Engineering and Solution Behavior, Chem. Eur. J. 23, (2017) 3432-3437.




[3] Y. W. Li, L. Y. Guo, H. F. Su, M. Jagodic, M. Luo, X. Q. Zhou, S. Y. Zeng, C. H. Tung, D. Sun,* L. S. Zheng, Two Unprecedented POM-Based Inorganic Organic Hybrids with Concomitant Heteropolytungstate and Molybdate, Inorg. Chem., 56 (2017)  2481-2489.




[4] J. H. Xu, L. Y. Guo, H. F. Su, X. Gao, X. F. Wu, W. G. Wang,* C. H. Tung,  D. Sun,* L. S. Zheng, A Heptanuclear CoII5CoIII2 Cluster as Efficient Water Oxidation Catalyst, Inorg. Chem., 56 (2017)  1591-1598.




[5] X. Y. Li, Z. Wang, H. F. Su, S. Feng, M. Kurmoo, C. H. Tung,  D. Sun,* L. S. Zheng, Anion-Templated Nanosized Silver Clusters Protected by Mixed Thiolate and Diphosphine, Nanoscale 9 (2017) 3601-3608.



[6] X. Y. Li,  H. F. Su, M. Kurmoo, C. H. Tung,  D. Sun,* L. S. Zheng, Structure, Solution Assembly, Electroconductivity of Nanosized Argento-Organic-Cluster/Framework Templated by Chromate, Nanoscale 9 (2017) 5305-5314.


[7] X. P. Wang, W. M. Chen, H. Qi, X. Y. Li, C. Rajnak, Z. Y. Feng, M. Kurmoo,* R. Boca, C. J. Jia, C.-H. Tung, D. Sun,*  Solvent-Controlled Phase Transition of a CoII-Organic Framework: From Achiral to Chiral and Two to Three Dimensions, Chem. Eur. J. 23, (2017) xxxx-xxxxx. DOI: 10.1002/chem.201700474. (Selected as Very Important Paper).







2016年

[1]  Y. K. Deng, H. F. Su, J. H. Xu, W. G. Wang, M. Kurmoo, S. C. Lin, Y. Z. Tan, J. Jia, D. Sun,*  L. S. Zheng, Hierarchical Assembly of a {MnII15MnIII4} Brucite Disc: Step-by-Step Formation and Ferrimagnetism.  J. Am. Chem. Soc., 138, (2016) 1328-1334.

[2] X. Y. Li, H. F. Su, R. Q. Zhou, S. Feng, Y. Z. Tan, X. P. Wang, J. Jia, M. Kurmoo, D. Sun,* L. S. Zheng,  General Assembly of Twisted Trigonal-Prismatic Nonanuclear Silver(I) Clusters, Chem. Eur. J. 22, (2016)  3019-3028.

[3] Z. Wang, X. Y. Li, L. W. Liu, S. Q. Yu, Z. Y. Feng, C.-H. Tung, D. Sun,* Beyond Cluster: Supramolecular Networks Self-Assembled from Nanosized Silver Clusters and Inorganic Anions, Chem. Eur. J. 22, (2016)  6830-6836. (HOT PAPER and Inside Cover)

[4] H. Y. Zhuo, H. F. Su, Z. Z. Chao, W. Liu, S. A. Wang, L. Feng, G. L. Zhuang, S. C. Lin, M. Kurmoo, C. H. Tung, D. Sun,* L. S. Zheng,  High-Nuclear Organometallic Copper(I)–Alkynide Clusters: Thermochromic Near-Infrared Luminescence and Solution Stability, Chem. Eur. J. 22, (2016)  17619-17626. (HOT PAPER and Inside Cover)


[5] Z. H. Yan, X. Y. Li, L. W. Liu, S. Q. Yu, X. P. Wang, D. Sun,*  Single-crystal to single-crystal phase transition and segmented thermochromic luminescence in a dynamic 3D interpenetrated AgI coordination network.  Inorg. Chem., 55 (2016) 1096-1101.

[6] Z. Wang, G. L. Zhuang, Y. K. Deng, Z. Y. Feng, Z. Z. Cao, M. Kurmoo, C. H. Tung,  D. Sun,* Near-Infrared Emitters: Stepwise Assembly of Two Heteropolynuclear Clusters with Tunable AgI:ZnII Ratio,  Inorg. Chem., 55 (2016) 4757-4763.


[7] L. Y. Guo, S.-Y. Zeng, M. Jagodic, Q. D. Hu, S. X. Wang Z. Wang, D. Sun,* A Pyridazine-Bridged Sandwiched Cluster Incorporating Planar Hexanuclear Cobalt Ring and Bivacant Phosphotungstate,  Inorg. Chem., 55 (2016) 9006-9011.


[8] Z. Wang, Z. Jaglicic, L. L. Han, G. L. Zhuang, G. G. Luo, S.-Y. Zeng,  C. H. Tung, D. Sun,* Octanuclear Ni(II) cubes based on halogen-substituted pyrazolates: Synthesis, structure, electrochemistry and magnetism, CrystEngComm,  18, (2016) 3462-3471.



[9] L. Y. Guo, M. Jagodic, S.-Y. Zeng, Z. Wang, Z. Q. Shi, X. P. Wang, C. H. Tung, D. Sun,* pH-Controlled Assembly of Two Novel Dawson-Sandwiched Clusters Involving In Situ Reorganization of Trivacant α-[P2W15O56]12- into Divacant α-[P2W16O57]8-, Dalton. Trans.,  45, (2016) 8404-8411.


[10] F. Yang, Y.-K. Deng, L.-Y. Guo, H.-F. Su, Z. Jaglicic,* Z.-Y. Feng, G.-L. Zhuang,* S.-Y. Zeng,  D. Sun,* Structural, electrochemical, and magnetic analyses of a new octanuclear MnIII2MnII6 cluster with linked-defect cubane topology, CrystEngComm,  18, (2016) 1329 - 1336.

[11] W. F. Xie, L. Y. Guo, J. H. Xu, M. Jagodic, Z. Jaglicic, W. G. Wang, G. L. Zhuang, Z. Wang, C. H. Tung, D. Sun,* Multifaceted Bicubane Co4 Clusters: Magnetism, Photocatalytic Oxygen Evolution and Electrical Conductivity, Eur. J. Inorg. Chem., 2016, 3253-3261.

[12] J. H. Xu, Z. Wang, W. G. Yu, D. Sun,* Q. Zhang, C. H. Tung, W. G. Wang,* Kagome Cobalt(II)-Organic Layers as Robust Scaffolds for Highly Efficient Photocatalytic Oxygen Evolution, ChemSusChem, 6 (2016) 1146-1152.


[13] X. Han, W. M. Chen, X. G. Han,* Y. Z. Tan, D. Sun,* Nitrogen-rich MOF Derived Porous Co3O4/N-C Composite with Superior Performance in Lithium-Ion Batteries, J.  Mater. Chem. A, 4 (2016) 13040-13045.

[14] Z. Wang, R. Senanayake, C. M. Aikens, W. M. Chen, C. H. Tung, D. Sun,* Gold-Doped Silver Nanocluster [Au3Ag38(SCH2Ph)24X5]2- (X= Cl or Br), Nanoscale  8 (2016) 18905-18911. (Selected as 2016 Nanoscale HOT Article Collection and selected as Inside Cover)


[15] X.-P. Wang, L.-L. Han, Z. Wang, L.-Y. Guo, D. Sun,* Microporous Cd(II) metal-organic framework as fluorescent sensor for nitroaromatic explosives at the sub-ppm level, J. Mol. Struct., 1107 (2016) 1-6.


[16] X.-P. Wang, L.-L. Han, S.-J. Lin, X.-Y. Li, K. Mei, D. Sun,* Synthesis, structure and photoluminescence of three 2D Cd(II) coordination polymers based on varied dicarboxylate ligand, J. Coord. Chem, 69 (2016) 286-289.


[17] H. Zhang, L.-Y. Guo, Z. Xie, X. Xin,* D. Sun,* S. L. Yuan,* Tunable Aggregation-Induced Emission of Polyoxometalates via Amino Acid-Directed Self-Assembly and Their Application in Detecting Dopamine,  Langmuir 32 (2016)13736−13745.



2015年

[1] F. L. Liu, B. Kozlevcar, P. Strauch, G. L. Zhuang, L. Y. Guo, Z. Wang, D. Sun,* Robust Cluster Building Unit (CBU): Icosanuclear Heteropolyoxocopperate Templated by Carbonate, Chem. Eur. J. 21, (2015) 18847 – 18854.

[2] Z. H. Xu, L. L. Han, G. L. Zhuang, J. Bai, D. Sun,* In Situ Construction of Three Anion-Dependent Cu(I) Coordination Networks as Promising Heterogeneous Catalysts for Azide−Alkyne “Click” Reactions, Inorg. Chem., 54 (2015) 4737-4743.

[3] T.-P. Hu, Y.-Q. Zhao, Z. Jaglicic, K. Yu, X.-P. Wang, D. Sun,* Four Hybrid Materials Based on Preyssler P5W30 Polyoxometalate and First-Row Transition-Metal Complex,  Inorg. Chem., 54 (2015) 7415-7423.

[4] X. Y. Li, H.F. Su, K. Yu, Y.Z. Tan,*  X.-P. Wang, Y.Q. Zhao, D. Sun,* L. S. Zheng, Platonic solid templating Archimedean solid: An unprecedented nanometre-sized Ag37 cluster, Nanoscale 7 (2015) 8284-8288.

[5] Z. Bai,* Y. Zhang, Y. Zhang, C. Guo, B. Tang, D. Sun,* MOFs-derived porous Mn2O3 as high-performance anode material for Li-ion battery, J.  Mater. Chem. A, 3 (2015) 5266-5269  (ESI高被引论文).

[6] X. Y. Li, Y.Z. Tan, K. Yu, X.-P. Wang, Y.Q. Zhao, D. Sun,* L. S. Zheng, Atom-precise polyoxometalate-Ag2S core-shell nanoparticle, Chem-Asian J, 10 (2015), 1295-1298.

[7] X.-P. Wang, T.-P. Hu, D. Sun,* Luminescent silver(I) coordination architectures containing 2-aminopyrimidyl ligands, CrystEngComm, 17 (2015) 3393-3417. (Invited Highlight Paper & Inside Cover)

[8] L.-L. Han, T.-P. Hu, K. Mei, Z.-M. Guo, C. Yin, Y.-X. Wang, J. Zheng, X.-P. Wang, D. Sun,* Solvent-controlled three families of Zn(ii) coordination compounds: synthesis, crystal structure, solvent-induced structural transformation, supramolecular isomerism and photoluminescence, Dalton Trans, 44 (2015) 6052-6061.

[9] L.-L. Han, S.-N. Wang, Z. Jaglicic, S.-Y. Zeng, J. Zheng, Z.-H. Li, J.-S. Chen, D. Sun,* Synthesis, structural versatility and magnetic properties of a series of copper(II) coordination polymers based on bipyrazole and various dicarboxylate ligands, CrystEngComm, 17 (2015) 1405-1415.

[10] T.-P. Hu, Y.-Q. Zhao, K. Mei, S.-J. Lin, X.-P. Wang, D. Sun,* A novel silver(I)-Keggin-polyoxometalate inorganic–organic hybrid: a Lewis acid catalyst for cyanosilylation reaction,  CrystEngComm, 17 (2015)  5947-5952.

[11] L.-L. Han, Y.-X. Wang, Z.-M. Guo, C. Yin, T.-P. Hu, X.-P. Wang, D Sun* Synthesis, crystal structure, thermal stability, and photoluminescence of a 3-D silver(I) network with twofold interpenetrated dia-f topology, J. Coord. Chem, 68 (2015) 1754-1764.

[12] X.-P. Wang, Y.-Q. Zhao, Z. Jaglicic, S.-N. Wang, S.-J. Lin, X.-Y. Li, D. Sun,* Controlled in situ reaction for the assembly of Cu(II) mixed-ligand coordination polymers: synthesis, structure, mechanistic insights, magnetism and catalysis, Dalton Trans, 44 (2015) 11013-11020.

2014年


[1] S. Yuan, Y. K. Deng, D. Sun,* Unprecedented Second-Timescale Blue/GreenEmissions andIodine-Uptake-Induced Single-Crystal-to-Single-CrystalTransformation inZn-II/Cd-II Metal-Organic Frameworks, Chem-Eur J, 20 (2014)10093-10098.

[2] X. L. Zhao, F. L. Liu, L. L. Zhang, D. Sun,* R. M.Wang, Z. F. Ju, D. Q. Yuan,* D.F. Sun,* Achieving a Rare Breathing Behavior in a Polycatenated 2D to 3D Net through a Pillar-Ligand Extension Strategy, Chem-Eur. J, 20 (2014) 649-652.

[3] Y.-Q. Zhao, K. Yu, L.-W. Wang, Y. Wang, X.-P.Wang, D. Sun,* Anion-Induced Supramolecular Isomerism in Two Preyssler P5W30 Polyoxometalate-Based Hybrid Materials, Inorg Chem, 53 (2014) 11046-11050.

[4] F. L. Liu, Z. H. Xu, X. Y. Zhang, X. P. Wang, D. Sun,* Unusual N-H Activation of 2-Aminopyrimidine: Supramolecular Assembly into anAg-I Metal-Organic Framework, Chem-Asian J, 9 (2014) 452-456.

[5] L. L. Han, X. Y. Zhang, J. S. Chen, Z. H. Li, D. F.Sun,* X. P. Wang, D. Sun,* Silver(I)/Bipyrazole/Dicarboxylate InterpenetratedCoordination Networks: Spontaneous Chiral Resolution, Modulation of Topologies,Water Clusters, and Photoluminescences, Cryst Growth Des, 14 (2014) 2230-2239.

[6] L. L. Han, Z.H. Li, J. S. Chen, X. P. Wang, D. Sun,*Solution and Mechanochemical Syntheses of Two Novel Cocrystals: Ligand LengthModulated Interpenetration of Hydrogen-Bonded 2D 6(3)-hcb Networks Based on a Robust Trimeric Heterosynthon, Cryst Growth Des, 14 (2014) 1221-1226.

[7] S. Yuan, Y. K. Deng, W. M. Xuan, X. P. Wang, S. N.Wang, J. M. Dou, D. Sun,* Spontaneous chiral resolution of a 3D (3,12)-connected MOF with an unprecedented ttt topology consisting of cubic Cd-4(mu(3)-OH)(4) clusters and propeller-like ligands, CrystEngComm, 16 (2014) 3829-3833. (Inside Cover)

[8] S. Yuan, S. S. Liu, D. Sun*, Two isomeric Cu4I4 luminophores: solvothermal/mechanochemical syntheses, structures and thermochromic luminescence properties, CrystEngComm, 16 (2014) 1927-1933.

[9] Y.Q. Zhao, M.X. Fang, Z.H. Xu, X.P. Wang,* S.N.Wang, L.L. Han, X.Y. Li, D. Sun,* Construction of a crystalline Ag(I)coordination polymer based on a new ligand generated from unusual in situ aza-Michael addition reaction, CrystEngComm, 16 (2014) 3015-3019.  

[10] L. L. Han, T. P. Hu, J. S. Chen, Z. H. Li, X. P. Wang,Y. Q. Zhao, X. Y. Li, D. Sun,* Simultaneous encapsulation of an infiniteT4(0)A(0)6(0) water tape and discrete water hexamers in a hydrogen-bonded Ag(I) supramolecular framework, Dalton Trans, 43 (2014) 8774-8780.

[11] S. S. Liu, S. Yuan, X. Y. Li, S. Miao, Z. W. Yu,* X. P. Wang, D. Sun,* A 'kagome dual' (kgd) sheet based on triangular rigidligand: Synthesis, structure, photoluminescence and anion exchange properties, Inorg. Chim. Acta, 416 (2014) 195-199.

[12] S. S. Liu, S. Yuan, T. P. Hu, D. Sun,* A 3D Luminescent Metal-organic Framework Constructed from Cu4I4 Cubane Clusters andTriangular Imidazole Ligand, Z. Anorg. Allg. Chem., 640 (2014) 2030-2034.

[13] F. L. Liu, X. P. Wang, D. Sun,* Synthesis and crystal structure of a novel cadmium sulfate coordination polymer based on multidentate 2-(3-(4-(pyridin-4-yl)phenyl)-1H-1,2,4-triazol-5-yl)pyridine, J. Struc. Chem. 55 (2014) 932-936.

2013年

[1] F. Sun, Z. Yin, Q.Q. Wang, D. Sun, M.H. Zeng,* M. Kurmoo,* Tandem Postsynthetic Modification of a MetalOrganic Framework by Thermal Elimination and Subsequent Bromination: Effects on Absorption Properties and Photoluminescence, Angew Chem Int Ed, 52 (2013) 4538-4543. (Co-first author)

[2] D. Sun,* S. Yuan, H. Wang, H.-F. Lu, S.-Y. Feng,D.-F. Sun,* Luminescence thermochromism of two entangled copper-iodide networkswith a large temperature-dependent emission shift, Chem. Commun., 49 (2013) 6152-6154. (ESI高被引论文)

[3] D. Sun,* L.-L. Han, S. Yuan, Y.-K. Deng, M.-Z. Xu, D.-F. Sun, Four New Cd(II) Coordination Polymers with Mixed MultidentateN-Donors and Biphenyl-Based Polycarboxylate Ligands: Syntheses, Structures, and Photoluminescent Properties, Cryst. Growth Des., 13 (2013) 377-385. (ESI高被引论文)

[4] L. Fan, X. Zhang,* D. Li, D. Sun,* W. Zhang, J.Dou,* Supramolecular isomeric flat and wavy honeycomb networks: additive agenteffect on the ligand linkages, CrystEngComm, 15 (2013) 349-355.

[5] D. Sun,* L.L. Zhang, H. F. Lu, S. Y. Feng, D. F.Sun, Bright-yellow to orange-red thermochromic luminescence of an Ag6I-Zn2IIheterometallic aggregate, Dalton Trans., 42 (2013) 3528-3532.

[6] D. Sun,* M.-Z. Xu, S.-S. Liu, S. Yuan, H.-F. Lu,S.-Y. Feng, D.-F. Sun, Eight Zn(II) coordination networks based on flexible1,4-di(1H-imidazol-1-yl)butane and different dicarboxylates: crystalstructures, water clusters, and topologies, Dalton Trans., 42 (2013) 12324-12333.

[7] D. Sun,* H. Wang, H.-F. Lu, S.-Y. Feng, Z.-W.Zhang, G.-X. Sun, D.-F. Sun, Two birds with one stone: anion templatedball-shaped Ag56 and disc-like Ag20 clusters, Dalton Trans., 42 (2013) 6281-6284.

[8] S. Yuan, H. Wang, D.-X. Wang, H.-F. Lu, S.-Y.Feng, D. Sun,* Reactant ratio-modulated six new copper(I)-iodide coordinationcomplexes based on diverse [CumIm] aggregates and biimidazole linkers:syntheses, structures and temperature-dependent luminescence properties, CrystEngComm, 15 (2013) 7792-7802.

[9] S. Yuan, Y.-K. Deng, X.-P. Wang, D. Sun,* Atemperature-sensitive luminescent Ag20 nanocluster templated by carbonate insitu generated from atmospheric CO2 fixation, New J. Chem.,37 (2013) 2973-2977.

[10] D. Sun,* F.-J. Liu, R.-B. Huang, L.-S. Zheng,Structural diversity of Ag/3-nitrophthalate coordination polymers controlled bysolvent and induction agent, CrystEngComm, 15 (2013) 1185-1193.

2012年

[1] X. Zhao, L. Zhang, H. Ma, D. Sun,* D. Wang, S. Feng, D. F. Sun,* Solvent-controlled Cd(II) metal-organic frameworksconstructed from a tetrapodal silicon-based linker, RSC Adv., 2 (2012) 5543-5549.

[2] X. Zhao, X. Wang, S. Wang, J. Dou, P. Cui, Z.Chen, D. Sun,* X. Wang, D. F. Sun,* Novel Metal-Organic Framework Based onCubic and Trisoctahedral Supermolecular Building Blocks: Topological Analysisand Photoluminescent Property, Cryst. Growth Des., 12 (2012) 2736-2739.

[3] X.-T. Zhang, D. Sun,* B. Li,* L.-M. Fan, B. Li,P.-H. Wei, Unusual High Thermal Stablility of a 2D-3D Polycatenated Fe(II)Metal-Organic Framework Showing Guest-Dependent Spin-Crossover Behavior andHigh Spin-Transition Temperature, Cryst. Growth Des.,12 (2012) 3845-3848.

[4] X.-T. Zhang, L.-M. Fan, X. Zhao,* D. Sun,* D.-C.Li, J.-M. Dou,* Syntheses, crystal structures, and properties of fivemixed-ligand coordination polymers based on novel quaterphenyl-2,5,2,5-tetracarboxylicacid ligand, CrystEngComm, 14 (2012) 2053-2061.

[5] F. Dai, D. Sun,* W. Sun, Y.-Q. Liu, D. F. Sun,* Conformation variation of tris(2-carboxyethyl)isocyanuric acid induced bycocrystallized N-heterocyclic organic molecules, CrystEngComm, 14 (2012)1376-1381.

[6] Y.-H. Li, D. Sun,* H.-J. Hao, Y. Zhao, R.-B.Huang,* L.-S. Zheng, Three novel organosilver(I) coordination networksconstructed from diallylmelamine and polycarboxylates incorporatingsilver-vinyl bonding, Dalton Trans., 41 (2012) 2289-2295.

[7] J. Sun, Y.-H. Wei, F.-L. Liu, D. Sun,* Syntheses,crystal structures and photoluminescent properties of silver(I) and cadmium(II)coordination polymers constructed from flexible hexadentate di-Schiff baseligands, RSC Adv., 2 (2012) 10189-10194.

[8] D. Sun,* L. Zhang, Z. Yan, D. F. Sun,* StepwiseConstruction of a AgI9-CuII4 Heterometallic Cluster Incorporating Two UnusualVertex-Shared Trigonal-Bipyramidal Silver Polyhedra, Chem.-Asian J., 7 (2012)1558-1561.

[9] D. Sun,* Z.-H. Yan, M. Liu, H. Xie, S. Yuan, H.Lu, S. Feng, D. F. Sun,* Three- and Eight-Fold Interpenetrated ThSi2Metal-Organic Frameworks Fine-Tuned by the Length of Ligand, Cryst. Growth Des., 12 (2012) 2902-2907.

[10] D. Sun,* Z.-H. Yan, Y.-K. Deng, S. Yuan, L.Wang,* D.-F. Sun, Two novel entangled metal-organic networks constructed from4,4-bis(2-methylimidazol-1-ylmethyl)biphenyl and dicarboxylates: From polycatenated 2D+2D - 3D framework to polyrotaxane-like 2D+2D - 2D layer, CrystEngComm, 14 (2012) 7856-7860.

[11] F.-J. Liu, D. Sun,* H.-J. Hao, R.-B. Huang,*L.-S. Zheng, 3D - 3D interpenetrated and 2D - 3D polycatenated Ag(I) networksconstructed from 1,4-bis(2-methylimidazol-1-ylmethyl)benzene and dicarboxylates, CrystEngComm, 14 (2012) 379-382.

[12] D. Sun,* F.-J. Liu, R.-B. Huang, L.-S. Zheng,Three guest-dependent nitrate-water aggregations encapsulated insilver(I)-bipyridine supramolecular frameworks, CrystEngComm, 14 (2012) 7872-7876.

[13] F.-J. Liu, D. Sun,* H.-J. Hao, R.-B. Huang,* L.-S. Zheng, Anion-Controlled Assembly of Silver(I)/AminobenzonitrileCompounds: Syntheses, CrystalStructures, and Photoluminescence Properties, Cryst. Growth Des., 12 (2012)354-361.

2011年7月-12月

[1] D. Sun,* F.-J. Liu, R.-B. Huang,* L.-S. Zheng,Anionic Heptadecanuclear Silver(I) Cluster Constructed from in Situ Generated2-Mercaptobenzoic Acid and a Sulfide Anion, Inorg. Chem., 50 (2011)12393-12395.

[2] D. Sun,* F.-J. Liu, H.-J. Hao, R.-B. Huang,* L.-S.Zheng, Different water clusters dependent on long-chain dicarboxylates in twoAg(I) coordination polymers: Synthesis, structure and thermal stability, J. Mol Struct., 1004 (2011) 313-318.

[3] D. Sun,* R.-B. Huang, L.-S. Zheng, Halogen Bondsin Two Silver(I) Mixed-ligand Supramolecular Frameworks: Synthesis, Structureand Photoluminescence, Z. Naturforsch. B, 66 (2011) 1035-1041.

[4] T. Hu,* X. Zhao, X. Hu, Y. Xu, D. Sun,* D. F.Sun,* Two novel isomeric organic anion-water aggregations: 1D tape and 3D2-fold interpenetrated diamond network, RSC Adv., 1 (2011) 1682-1686.

[5] H.-J. Hao, D. Sun,* F.-J. Liu, R.-B. Huang,* L.-S.Zheng, Discrete Octamer Water Cluster and 1D T5(2) Water Tape Trapped in TwoLuminescent Zn(II)/1,2-Bis(imidazol-1-yl) ethane/Dicarboxylate Hosts: From 2D(4,4) Net to 3D 5-Fold Interpenetrated Diamond Network, Cryst. Growth Des., 11 (2011) 5475-5482.

[6] P. Cui, J. Wu, X. Zhao, D. Sun,* L. Zhang, J. Guo,D. F. Sun,* Two Solvent-Dependent Zinc(II) Supramolecular Isomers: Rare kgd andLonsdaleite Network Topologies Based on a Tripodal Flexible Ligand, Cryst.Growth Des., 11 (2011) 5182-5187. (Citation = 69)

2011年之前 (攻读博士学位期间)

[1] D. Sun, G.-G. Luo, N. Zhang, R.-B. Huang,* L.-S.Zheng, Simultaneous self-assembly of a cage-like silver(I) complexencapsulating an Ag6 neutral cluster core and carbon dioxide fixation, Chem.Commun., 47 (2011) 1461-1463.(Citation = 69)

[2] D. Sun, D.-F. Wang, X.-G. Han, N. Zhang, R.-B.Huang,* L.-S. Zheng, Stepwise assembly of two 3d-4d heterometallic coordinationpolymers based on a hexanuclear silver(I) metalloligand, Chem. Commun., 47 (2011) 746-748.(Citation = 84)

[3] D. Sun, C.-F. Yang, H.-R. Xu, H.-X. Zhao, Z.-H.Wei, N. Zhang, L.-J. Yu, R.-B. Huang,* L.-S. Zheng, Synthesis, characterizationand property of a mixed-valent Ag-I/Ag-II coordination polymer, Chem. Commun.,46 (2010) 8168-8170.(Citation = 54)

[4] D. Sun, Y.-H. Li, H.-J. Hao, F.-J. Liu, Y.-M. Wen,R.-B. Huang,* L.-S. Zheng, Solvent-Controlled Rare Case of a Triple HelicalMolecular Braid Assembled from Proton-Transferred Sebacic Acid, Cryst. GrowthDes., 11 (2011) 3323-3327.

[5] D. Sun, D.-F. Wang, N. Zhang, R.-B. Huang,* L.-S.Zheng, Nonamer Water Cluster Encapsulated in a Heterometallic SupramolecularComplex, Cryst. Growth Des., 10 (2010) 5031-5033.

[6] D. Sun, Z.-H. Wei, D.-F. Wang, N. Zhang, R.-B.Huang,* L.-S. Zheng, Acetonitrile-Templated Assembly of a Laminar Silver(I)Phthalate Coordination Polymer, Cryst. Growth Des., 11 (2011) 1427-1430.

[7] D. Sun, H.-R. Xu, C.-F. Yang, Z.-H. Wei, N. Zhang,R.-B. Huang,* L.-S. Zheng, Encapsulated Diverse Water Aggregates in TwoAg(I)/4,4-Bipyridine/Dicarboxylate Hosts: 1D Water Tape and Chain, Cryst.Growth Des., 10 (2010) 4642-4649. .(Citation =  91)

[8] D. Sun, N. Zhang, R.-B. Huang,* L.-S. Zheng,Series of Ag(I) Coordination Complexes Derived from Aminopyrimidyl Ligands and Dicarboxylates: Syntheses, Crystal Structures, and Properties, Cryst. Growth Des., 10 (2010) 3699-3709.(Citation = 125)

[9] D. Sun, H.-J. Hao, F.-J. Liu, H.-F. Su, R.-B.Huang,* L.-S. Zheng, Syntheses, crystal structures and photoluminescentproperties of two novel Ag(I) coordination polymers with benzoguanamine andpyrazine-carboxylate ligands: From 1D helix to 1D - 2D interdigitation, CrystEngComm, 14 (2012) 480-487.

[10] D. Sun, Y.-H. Li, H.-J. Hao, F.-J. Liu, Y. Zhao,R.-B. Huang,* L.-S. Zheng, Syntheses, structures and photoluminescentproperties of a series of Ag(I) coordination architectures based on2,4-diamino-6-methyl-1,3,5-triazine and dicarboxylates: from a 0D discretemolecule to a 3D infinite network, CrystEngComm, 13 (2011) 6431-6441.

[11] D. Sun, Y.-H. Li, S.-T. Wu, H.-J. Hao, F.-J. Liu,R.-B. Huang,* L.-S. Zheng, An unprecedented (4,24)-connected metal-organicframework sustained by nanosized Ag12 cuboctahedral node, CrystEngComm, 13(2011) 7311-7315.

[12] D. Sun, F.-J. Liu, H.-J. Hao, Y.-H. Li, N. Zhang,R.-B. Huang,* L.-S. Zheng, A novel arenedisulfonate-templated 1D silver ladderconstructed from 4-aminobenzonitrile ligand, CrystEngComm, 13 (2011) 5661-5665.

[13] D. Sun, D.-F. Wang, F.-J. Liu, H.-J. Hao, N.Zhang, R.-B. Huang,* L.-S. Zheng, Design and synthesis of 3d-4d heterometalliccoordination complexes based on a nonanuclear silver(I) metallatecton, CrystEngComm, 13 (2011) 2833-2836.

[14] D. Sun, Z.-H. Wei, C.-F. Yang, D.-F. Wang, N.Zhang, R.-B. Huang,* L.-S. Zheng, pH-Dependent Ag(I) coordination architecturesconstructed from 4-cyanopyridine and phthalic acid: from discrete structure to2D sheet, CrystEngComm, 13 (2011) 1591-1601. .(Citation =  94)

[15] D. Sun, Q.-J. Xu, C.-Y. Ma, N. Zhang, R.-B.Huang,* L.-S. Zheng, Self-assembly, thermal stability and photoluminescence oftwo mixed-ligand silver(I) networks via 2D-2D and 2D-3D parallel interpenetrationof (4,4) nets, CrystEngComm, 12 (2010) 4161-4167.

[16] D. Sun, D.-F. Wang, N. Zhang, F.-J. Liu, H.-J.Hao, R.-B. Huang,* L.-S. Zheng, Capture and activation of aerial CO2 bycarbamoylation of L-threonine in a Ag(I) supramolecular framework, Dalton Trans,40 (2011) 5677-5679.

[17] D. Sun, Y.-H. Li, F.-J. Liu, H.-J. Hao, R.-B.Huang,* L.-S. Zheng, Characterization of an unprecedented (ethanol)4 cluster ina novel photoluminescent silver(I) coordination polymer, Inorg. Chem. Commun.,14 (2011) 1871-1875.

[18] D. Sun, G.-G. Luo, Q.-J. Xu, N. Zhang, Y.-C. Jin,H.-X. Zhao, L.-R. Lin, R.-B. Huang,* L.-S. Zheng, A novel lamella 2D Ag(I)coordination polymer of graphite-like structure featuring short interlayerdistance, Inorg. Chem. Commun., 12 (2009) 782-784.

[19] D. Sun, G.-G. Luo, N. Zhang, Q.-J. Xu, Y.-C. Jin,Z.-H. Wei, C.-F. Yang, L.-R. Lin, R.-B. Huang,* L.-S. Zheng, A lamella 2Dsilver(I) coordination polymer constructed from in situ generated2-mercaptobenzoic acid, Inorg. Chem. Commun., 13 (2010) 306-309.

[20] D. Sun, G.-G. Luo, N. Zhang, Q.-J. Xu, C.-F.Yang, Z.-H. Wei, Y.-C. Jin, L.-R. Lin, R.-B. Huang,* L.-S. Zheng, A novel 3Dsilver(I) coordination polymer exhibiting unprecedented m3- and m4-bondingmodes of 2-aminopyrazines, Inorg. Chem. Commun., 13 (2010) 290-293.

[21] D. Sun, Z.-H. Wei, C.-F. Yang, N. Zhang, R.-B.Huang,* L.-S. Zheng, Synthesis and crystal structure of an Ag20 clusterincorporating in situ generated bipodal ArP(OEt)S2- and tripodal ArPOS22-ligands (Ar=4-methoxyphenyl), Inorg. Chem. Commun., 13 (2010) 1191-1194.

[22] D. Sun, N. Zhang, R.-B. Huang,* L.-S. Zheng, Ag3triangle and Ag4 rectangle supported by deprotonated aminopyrimidyl derivativesand bis(diphenylphosphino)methane, Inorg. Chem. Commun., 14 (2011) 1039-1042.

[23] D. Sun, N. Zhang, Q.-J. Xu, R.-B. Huang,* L.-S.Zheng, A new clover-shaped trinuclear uranium(VI) complex: Synthesis, structureand photoluminescence property, Inorg. Chem. Commun., 13 (2010) 859-862.

[24] D. Sun, F.-J. Liu, H.-J. Hao, Y.-H. Li, R.-B.Huang,* L.-S. Zheng, Six low-dimensional silver(I) coordination complexesderived from 2-aminobenzonitrile and carboxylates, Inorg. Chim. Acta., 387(2012) 271-276.

[25] D. Sun, N. Zhang, Q.-J. Xu, Z.-H. Wei, R.-B.Huang,* L.-S. Zheng, Assembly of 1D, 2D and 3D silver(I) coordination polymerswith nitrilotriacetate and 2-aminopyrimidyl mixed ligands, Inorg. Chim. Acta.,368 (2011) 67-73.

[26] D. Sun, F.-J. Liu, H.-J. Hao, R.-B. Huang,* L.-S.Zheng, Coexistent Ag center dot center dot center dot Ag and Ag center dotcenter dot center dot C interactions in three photoluminescent silver(I)coordination networks based on o-, m-, p-methylbenzoic acid, J. Mol. Struct,1006 (2011) 475-482.

[27] D. Sun, G.-G. Luo, N. Zhang, Z.-H. Wei, C.-F.Yang, Q.-J. Xu, R.-B. Huang,* L.-S. Zheng, Influence of aminopyrimidylderivatives on the supramolecular architectures and abundant nonvalentinteractions of silver 5-nitroisophthalate coordination polymers, J. Mol.Struct, 967 (2010) 147-152.

[28] D. Sun, N. Zhang, Z.-H. Wei, C.-F. Yang, R.-B.Huang,* L.-S. Zheng, The solid-state structures of two photoluminescent 2Dsilver(I) arenedisulfonate incorporating aminopyrimidyl ligands: Substituentsinfluence on pi center dot center dot center dot pi interaction, J. Mol.Struct, 981 (2010) 80-85.

[29] D. Sun, N. Zhang, Q.-J. Xu, R.-B. Huang,* L.-S.Zheng, Syntheses, structures and luminescent properties of silver(I)coordination polymers based on aminopyrimidyl derivatives and 1,2,3,4-butanetetracarboxylicacid, J. Mol. Struct, 975 (2010) 17-22.

[30] D. Sun, N. Zhang, Q.-J. Xu, G.-G. Luo, R.-B.Huang,* L.-S. Zheng, Self-assembly of silver(I) coordination polymers fromaminopyrimidyl derivatives and malonate acid: From 1D chain to 2D layer, J. Mol.Struct, 970 (2010) 134-138.

[31] D. Sun, N. Zhang, Q.-J. Xu, G.-G. Luo, R.-B.Huang,* L.-S. Zheng, A novel silver(I)-containing supramolecular frameworkincorporating eight different hydrogen bond motifs, J. Mol. Struct, 969 (2010)176-181.

[32] D. Sun, N. Zhang, Q.-J. Xu, R.-B. Huang,* L.-S.Zheng, A novel 3D silver(I) supramolecular framework assembled from hybridligands incorporating Ag-C interactions, J. Organomet. Chem., 695 (2010)1598-1602.

[33] D. Sun, G.-G. Luo, N. Zhang, J.-H. Chen, R.-B.Huang,* L.-R. Lin, L.-S. Zheng, Influence of dicarboxylic acids onself-assembly process: Syntheses and structural characterization of new Ag(I)complexes derived from mixed ligands, Polyhedron, 28 (2009) 2983-2988.

[34] D. Sun, G.-G. Luo, N. Zhang, Q.-J. Xu, R.-B.Huang,* L.-S. Zheng, Syntheses, structures, photoluminescences of silver(I)coordination polymers with 2-aminopyrazine and varied dicarboxylate ligands,Polyhedron, 29 (2010) 1243-1250.

[35] D. Sun, N. Zhang, G.-G. Luo, Q.-J. Xu, R.-B.Huang,* L.-S. Zheng, Assembly of silver(I) coordination polymers incorporatingpyromellitic acid and N-heterocyclic ligands, Polyhedron, 29 (2010) 1842-1848.

[36] D. Sun, C.-F. Yang, Z.-H. Wei, G.-G. Luo, N.Zhang, Q.-J. Xu, R.-B. Huang,* L.-S. Zheng, Self-assembly of a NovelThree-dimensional Silver(I) Supramolecular Framework from Cationic Chains andAnionic Sheets, Z. Naturforsch. B, 65 (2010) 152-156.

[37] D. Sun, G.-G. Luo, N. Zhang, Q.-J. Xu, Z.-H. Wei,C.-F. Yang, L.-R. Lin, R.-B. Huang,* L.-S. Zheng, A Novel 3D PhotoluminescentSilver(I) Coordination Polymer Featuring Unusual m4-Bonded and Usual m2-Bonded2-Aminopyrazine, Bull. Chem. Soc. Jpn. 83 (2010) 173-175.

[38] D. Sun, G.-G. Luo, N. Zhang, Z.-H. Wei, C.-F.Yang, R.-B. Huang,* L.-S. Zheng, Capturing a Metastable Silver(I) Compound of Pyrazine-2,3-dicarboxylic Acid, Chem. Lett., 39 (2010) 190-191.


                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                           

【科研项目】

1、山东大学自主创新基金(2011GN030),2011年-2013年,负责人 6W


2、山东省博士后创新项目专项资金(201101007), 2012年-2013年,负责人 8W


3、中国博士后基金面上项目(第51批), (2012M511492),2012.6-2014.7,负责人 5W


4、国家自然科学基金青年基金(21201110), 2013.1-2015.12,负责人 25W


5、中国博士后基金特别资助(第六批) (2013T60663),2013.6-2015.7,负责人 15W


6、山东省优秀中青年科学家科研奖励基金(BS2013CL010),2013.10-2015.10,负责人 6W


7、山东大学青年学者未来计划 (2015WLJH24),2015.6-2019.6,负责人 50W


8、山东大学基本科研业务费交叉学科培育项目 (2015JC045),2015.6-2017.6,负责人 40W


9、国家自然科学基金青年基金面上项目 (21571115),2016.1-2019.12,负责人 60 W

 

【科研成果】

 

1、2012年山东高等学校优秀科研成果奖 一等奖 (第贰位)

 

2、2014年山东高等学校优秀科研成果奖 二等奖 (第壹位)

 

3、2015年获美国化学会(ACS) Membership Award

 

【所获专利】

【联合培养情况】

【拟招收研究生情况】

课题组成员:

研究生:

韩璐璐  (导师:孙頔)2012.9-2015.6, 硕士研究生,方向:功能配合物化学,联吡唑构筑的功能配合物

(获得2014年度国家奖学金,2014年度山东大学研究生优秀学术成果奖,2014年度山东大学2014年度优秀研究生,2014年度山东大学化学与化工学院“晨曦杯”杰出奖,2015年度省级优秀毕业生,山大省优秀硕士论文奖)

赵雅琴  (导师:王兴坡、孙頔)2012.9-2015.6, 硕士研究生,方向:功能配合物化学,杂多酸构筑的新型功能材料

(获得2014年度山东大学研究生科研成果奖,2014年度山东大学优秀研究生,2014年度山东大学化学与化工学院“晨曦杯”专业优胜奖)

李小雨(导师:王兴坡、孙頔)2013.9-至今,硕士研究生,方向:原子簇化学,高核银簇组装功能及其研究(2015年度国家奖学金,2015年度山东大学校长奖学金,2016年度山东大学研究生优秀学术成果奖三等奖)

郭玲玉(导师:王兴坡、孙頔)2014.9-至今,硕士研究生,方向:功能配合物化学,缺位杂多酸构筑的新型杂化材料 (学业奖学金一等,2016年度IKA研究生创新奖)


王芝   (导师:孙頔)2014.9-至今,硕士研究生,方向:原子簇化学,高核银簇组装及功能2016年度国家奖学金,2016年度山东大学校长奖学金,2016年度山东大学化学与化工学院“晨曦杯”杰出奖)

本科生:

袁帅    2009级本科化学专业)参与项目时间2012.9 -2013.6Texas A&M University,Hong-Cai JOE Zhou课题组

徐梦真  2010级本科化学专业)参与项目时间2013.3 -2014.6,保送北京大学

刘珊珊  2010级本科化工专业)参与项目时间2013.9 -2014.6,保送天津大学

方明响  2011级本科化学专业)参与项目时间2013.3 -2013.7,保送山东大学

邓永恺  2011级本科泰山学堂化学专业)参与项目时间2012.3 -至今,已保送厦门大学

梅开    2011级本科化学专业)参与项目时间2014.9 -至今,已保送东北师范大学

高巧峰  2013级本科化学专业)参与项目时间2014.9 -至今

刘力玮  2013级本科化学专业)参与项目时间2014.9 -至今

于思绮  2013级本科化学专业)参与项目时间2014.9 -至今

冯声    2013级本科化学专业)参与项目时间2014.9 -至今

周瑞琪  2013级本科化学专业)参与项目时间2014.9 -至今

肖宇露  2013级本科化学专业)参与项目时间2014.9 -至今

李筱婷  2013级本科化学专业)参与项目时间2014.9 -至今

蔺淑洁  2012级本科化工专业)参与项目时间2014.9 -至今

李小艺  2012级本科化学专业)参与项目时间2013.3 -至今

苗澍    2012级本科化学专业)参与项目时间2013.3 -至今

尹琛    2012级本科化学专业)参与项目时间2014.9 -至今

王雅馨  2012级本科化学专业)参与项目时间2014.3 -至今

郭志敏  2012级本科化学专业)参与项目时间2014.3 -至今

王迎    2012级本科化学专业)参与项目时间2014.3 -至今

王力维  2012级本科化学专业)参与项目时间2014.3 -至今

付杰    2011级本科化学专业)参与项目时间2013.3 -2013.7

陈江山  2011级本科化学专业)参与项目时间2013.3 -至今

李忠辉  2011级本科化学专业)参与项目时间2013.3 -至今

欢迎优秀的研究生(每年3-4人)和本科生(不限人数)加入本题组并参与相关科研项目,读研三年期间,表现突出的学生可获得不低于2万的助研津贴!!

本课题组经常有外国专家/学生来访,参与项目的学生有机会和国外知名专家/学生进行面对面交流,研究生就读期间至少提供1次短期出国交流机会,1-2次参加国内外学术会议的机会。望有志者青年加盟本课题组。

 

test